Communication: inferring the equation of state of a metastable hard-sphere fluid from the equation of state of a hard-sphere mixture at high densities.

نویسندگان

  • Andrés Santos
  • Santos B Yuste
  • Mariano López de Haro
چکیده

A possible approximate route to obtain the equation of state of the monodisperse hard-sphere system in the metastable fluid region from the knowledge of the equation of state of a hard-sphere mixture at high densities is discussed. The proposal is illustrated by using recent Monte Carlo simulation data for the pressure of a binary mixture. It is further shown to exhibit high internal consistency.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 135 18  شماره 

صفحات  -

تاریخ انتشار 2011